A Numerical Investigation of Methane Air Partially Premixed Flames at Elevated Pressures

A numerical investigation of high pressure, counterflow methane-air partially premixed flames (PPFs) is presented to characterize the effect of pressure on flame structure. Four different mechanisms, namely GRI-2.11, GRI-3.0, the San Diego, and the C2 mechanisms have been examined. The mechanisms have been validated by comparing the predicted laminar flame speeds with experimental data. While there is excellent agreement between the measured and predicted laminar flame speeds based on these mechanisms, there are noticeable discrepancies amongst the mechanisms for the prediction of high-pressure PPFs. The GRI 3.0 mechanism is used to examine the detailed PPF structure at elevated pressures. At low pressures, the PPF exhibits a typical double flame structure that consists of rich premixed and nonpremixed reaction zones, and the separation distance between the reaction zones decreases with increasing pressure. However, for pressure above 10 atm, the separation distance becomes nearly independent of pressure. In addition, a critical pressure is observed, above which the PPF structure exhibits anomalous behavior, characterized by the presence of endothermic reactions and the production of CO in the region between the two reaction zones. A rate of production analysis revealed that the anomalous behavior is attributable to the following reactions: HþH2O ! OHþH2; CH2COþM ! CH2þ COþM, and HCOþM ! Hþ COþM. The critical pressure at which this behavior is first observed increases with the increase in equivalence ratio and=or Received 22 October 2004; accepted 14 July 2006. This research was supported by the NSF Combustion and Plasma Systems Program for which Dr. Linda Blevins is the Program Director. Many useful discussions with Dr. Ishwar K Puri of Virginia Tech, and Drs. Tamas Turanyi and Istvan Gyula Zsely of Eotvos University are appreciated. Address correspondence to [email protected] Combust. Sci. and Tech., 179: 1085–1112, 2007 Copyright Q Taylor & Francis Group, LLC ISSN: 0010-2202 print/1563-521X online DOI: 10.1080/00102200600910882